IndiumV3, Main, Repository, bibRecord, 002261

Thermoanalytical study of precursors for In2S3 thin films deposited by spray pyrolysis

Identifieur interne : 002261 ( Main/Repository ); précédent : 002260; suivant : 002262

Thermoanalytical study of precursors for In2S3 thin films deposited by spray pyrolysis

Auteurs : RBID : Pascal:12-0173597

Descripteurs français

Pascal (Inist)
- Analyse thermique, Précurseur, Indium Sulfure, Couche mince, Analyse thermique différentielle, Thermogravimétrie, Thiourée, Pyrolyse, Indium Complexe, Diffraction RX, Analyse gaz, Dégagement gazeux, Spectrométrie IR, Transformation Fourier, FT IR, Dépôt par pyrolyse d'aérosol, Analyse gaz dégagé.

English descriptors

KwdEn :
- Differential thermal analysis, Evolved gas analysis, Fourier transformation, Gas analysis, Gas release, Indium Complexes, Indium Sulfides, Infrared spectrometry, Precursor, Pyrolysis, Spray pyrolysis, Thermal analysis, Thermogravimetry, Thin film, Thiourea, X ray diffraction.

Abstract

Thermal decomposition of precursors for In₂S₃ thin films obtained by drying aqueous solutions of InCl₃ and SC(NH₂)₂ at the In:S molar ratios of 1:3 (1) and 1:6 (2) was monitored by simultaneous TG/DTA/EGA-FTIR measurements in the dynamic 80%Ar + 20%O₂ atmosphere. XRD and FTIR were used to identify the dried precursors and products of the thermal decomposition. The precursors 1 and 2 are complex compounds, while in 2 free SC(NH₂)₂ is also present. The thermal degradation of 1 and 2 in the temperature range of 30-900 °C consists of four mass loss steps, the total mass loss being 89.1 and 78.5%, respectively. According to XRD, In₂S₃ is formed below 300 °C, crystalline In_2.24(NCN)₃ is detected only in 1 above 520 °C and In₂O₃ is the final decomposition product at 900 °C. The gaseous species evolved include CS₂, NH₃, H₂NCN, HNCS, which upon oxidation yield also COS, SO₂, HCN and CO₂.

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Le document en format XML

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S<sub>3</sub>
 thin films deposited by spray pyrolysis</title>
<author><name sortKey="Otto, K" uniqKey="Otto K">K. Otto</name>
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<author><name sortKey="Mere, A" uniqKey="Mere A">A. Mere</name>
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<term>Fourier transformation</term>
<term>Gas analysis</term>
<term>Gas release</term>
<term>Indium Complexes</term>
<term>Indium Sulfides</term>
<term>Infrared spectrometry</term>
<term>Precursor</term>
<term>Pyrolysis</term>
<term>Spray pyrolysis</term>
<term>Thermal analysis</term>
<term>Thermogravimetry</term>
<term>Thin film</term>
<term>Thiourea</term>
<term>X ray diffraction</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Analyse thermique</term>
<term>Précurseur</term>
<term>Indium Sulfure</term>
<term>Couche mince</term>
<term>Analyse thermique différentielle</term>
<term>Thermogravimétrie</term>
<term>Thiourée</term>
<term>Pyrolyse</term>
<term>Indium Complexe</term>
<term>Diffraction RX</term>
<term>Analyse gaz</term>
<term>Dégagement gazeux</term>
<term>Spectrométrie IR</term>
<term>Transformation Fourier</term>
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<front><div type="abstract" xml:lang="en">Thermal decomposition of precursors for In<sub>2</sub>
S<sub>3</sub>
 thin films obtained by drying aqueous solutions of InCl<sub>3</sub>
 and SC(NH<sub>2</sub>
)<sub>2</sub>
 at the In:S molar ratios of 1:3 (1) and 1:6 (2) was monitored by simultaneous TG/DTA/EGA-FTIR measurements in the dynamic 80%Ar + 20%O<sub>2</sub>
 atmosphere. XRD and FTIR were used to identify the dried precursors and products of the thermal decomposition. The precursors 1 and 2 are complex compounds, while in 2 free SC(NH<sub>2</sub>
)<sub>2</sub>
 is also present. The thermal degradation of 1 and 2 in the temperature range of 30-900 °C consists of four mass loss steps, the total mass loss being 89.1 and 78.5%, respectively. According to XRD, In<sub>2</sub>
S<sub>3</sub>
 is formed below 300 °C, crystalline In<sub>2.24</sub>
(NCN)<sub>3</sub>
 is detected only in 1 above 520 °C and In<sub>2</sub>
O<sub>3</sub>
 is the final decomposition product at 900 °C. The gaseous species evolved include CS<sub>2</sub>
, NH<sub>3</sub>
, H<sub>2</sub>
NCN, HNCS, which upon oxidation yield also COS, SO<sub>2</sub>
, HCN and CO<sub>2</sub>
.</div>
</front>
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 thin films deposited by spray pyrolysis</s1>
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<fC01 i1="01" l="ENG"><s0>Thermal decomposition of precursors for In<sub>2</sub>
S<sub>3</sub>
 thin films obtained by drying aqueous solutions of InCl<sub>3</sub>
 and SC(NH<sub>2</sub>
)<sub>2</sub>
 at the In:S molar ratios of 1:3 (1) and 1:6 (2) was monitored by simultaneous TG/DTA/EGA-FTIR measurements in the dynamic 80%Ar + 20%O<sub>2</sub>
 atmosphere. XRD and FTIR were used to identify the dried precursors and products of the thermal decomposition. The precursors 1 and 2 are complex compounds, while in 2 free SC(NH<sub>2</sub>
)<sub>2</sub>
 is also present. The thermal degradation of 1 and 2 in the temperature range of 30-900 °C consists of four mass loss steps, the total mass loss being 89.1 and 78.5%, respectively. According to XRD, In<sub>2</sub>
S<sub>3</sub>
 is formed below 300 °C, crystalline In<sub>2.24</sub>
(NCN)<sub>3</sub>
 is detected only in 1 above 520 °C and In<sub>2</sub>
O<sub>3</sub>
 is the final decomposition product at 900 °C. The gaseous species evolved include CS<sub>2</sub>
, NH<sub>3</sub>
, H<sub>2</sub>
NCN, HNCS, which upon oxidation yield also COS, SO<sub>2</sub>
, HCN and CO<sub>2</sub>
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<s5>02</s5>
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<fC03 i1="02" i2="X" l="SPA"><s0>Precursor</s0>
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<s2>NC</s2>
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<s5>03</s5>
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<fC03 i1="03" i2="X" l="SPA"><s0>Indio Sulfuro</s0>
<s2>NC</s2>
<s2>NA</s2>
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<s5>04</s5>
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<fC03 i1="04" i2="X" l="SPA"><s0>Capa fina</s0>
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<s5>07</s5>
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<s5>07</s5>
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<fC03 i1="07" i2="X" l="SPA"><s0>Tiourea</s0>
<s5>07</s5>
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<fC03 i1="08" i2="X" l="FRE"><s0>Pyrolyse</s0>
<s5>08</s5>
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<fC03 i1="08" i2="X" l="ENG"><s0>Pyrolysis</s0>
<s5>08</s5>
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<s5>08</s5>
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<fC03 i1="09" i2="X" l="FRE"><s0>Indium Complexe</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>09</s5>
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<s2>NC</s2>
<s2>NA</s2>
<s5>09</s5>
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<fC03 i1="09" i2="X" l="SPA"><s0>Indio Complejo</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>09</s5>
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<fC03 i1="10" i2="X" l="FRE"><s0>Diffraction RX</s0>
<s5>10</s5>
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<fC03 i1="10" i2="X" l="ENG"><s0>X ray diffraction</s0>
<s5>10</s5>
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<fC03 i1="10" i2="X" l="SPA"><s0>Difracción RX</s0>
<s5>10</s5>
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<s5>32</s5>
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<s5>33</s5>
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<s5>35</s5>
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<s5>76</s5>
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<s4>CD</s4>
<s5>96</s5>
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<s4>CD</s4>
<s5>97</s5>
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<s4>CD</s4>
<s5>97</s5>
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<fN21><s1>129</s1>
</fN21>
</pA>
<pR><fA30 i1="01" i2="1" l="ENG"><s1>ESTAC 2010  European Symposium on Thermal Analysis and Calorimetry</s1>
<s2>10</s2>
<s3>Rotterdam NLD</s3>
<s4>2010-08-22</s4>
</fA30>
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Thermoanalytical study of precursors for In2S3 thin films deposited by spray pyrolysis

Thermoanalytical study of precursors for In2S3 thin films deposited by spray pyrolysis

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